Search results for "Homogeneous broadening"
showing 10 items of 10 documents
Argon broadening of the 13CO R(0) and R(7) transitions in the fundamental band at temperatures between 80 and 297K: comparison between experiment and…
2003
We present measurements of Ar-broadening parameters for the R(0) and R(7) lines in the fundamental band of13CO at eight temperatures from 80 to 297 K. The broadening parameters are determined by simultaneous least-squares fitting of spectra recorded using a frequency stabilized diode laser spectrometer. The comparison of the broadening parameter values for R(7) derived at room temperature and different pressures from different line profiles shows that an empirical line profile, which takes into account narrowing effects (Dicke narrowing and absorber speed dependence) but neglects any correlation between collisions, is able to describe the observed lines with constant values of the narrowing…
Low temperature optical spectroscopy of low-spin ferric hemeproteins
1996
We report the Soret absorption spectra (500-350 nm) of the cyanomet derivatives of human hemoglobin and horse myoglobin, in the temperature range 300-20 K and in two different solvents (65% v/v glycerol-water or 65% v/v ethylene glycol-water). In order to obtain information on stereodynamic properties of active site of the two hemeproteins, we perform an analysis of the band profiles within the framework of electron-vibrations coupling. This approach enables us to single out the various contributions to the spectral bandwidth, such as those arising from non-radiative decay of the excited electronic state (homogeneous broadening) and from the coupling of the electronic transition i) with hig…
Experimental Stark broadening studies of the CI transition 3s 1 P 1o − 3p 1 S 0 at 833.5 nm
2011
AbstractExperimental Stark broadening studies of the infrared CI transition 3s 1 P 1o − 3p 1 S 0 at 833.5 nm are reported for the first time. A high-current wall-stabilized arc, operated in a mixture of helium, argon, carbon dioxide and hydrogen, was applied as the plasma source. Radiation emitted from homogeneous and optically thin plasma layers was analyzed. Stark broadening studies of the selected CI transition and the hydrogen Balmer β line were performed. As expected from theoretical considerations, the CI line width depends linearly on the electron density of the plasma. Applying theoretical Stark broadening data for the Hgb line, the measured Stark widths of the CI line were calibrat…
Vibrational Signature of Water Molecules in Asymmetric Hydrogen Bonding Environments
2013
The O–H stretching vibrational modes of water molecules are sensitive to their local environments. Here, we applied effective normal-mode analysis to isolate contributions of each of the two hydrogen atoms to the vibrational modes ν1 and ν3 of water molecules in the liquid phase. We demonstrate that the decoupling of the two contributions fd and the frequency splitting of the vibrational modes Δω13 are inextricably related to the symmetry of the hydrogen bonding environment. We show that ambient liquid water modeled at the density functional level of theory exhibits the characteristics of an asymmetric environment with an average decoupling of 0.82 and a splitting of 137 inverse centimeters…
Experimental and theoretical Stark broadening studies of the hydrogen Paschen beta line.
2002
Experimental and theoretical Stark broadening studies of the Paschen beta line of hydrogen (lambda=1.28 microm) are reported. Line shape measurements were performed at electron densities of the plasma between 3.5 x 10(15) cm(-3) and 7.5 x 10(15) cm(-3), applying as the light source a wall-stabilized arc operated at atmospheric pressure in a helium-hydrogen gas mixture. The radiation of the plasma, emitted from nearly homogeneous plasma layers in the end-on direction, was registered with the use of a grating spectrometer equipped with a charge coupled device detector. The measured light outputs were calibrated against signals obtained from a tungsten strip radiation standard. The experimenta…
Photoluminescence spectral dispersion as a probe of structural inhomogeneity in silica
2011
We perform time-resolved photoluminescence measurements on point defects in amorphous silicon dioxide (silica). In particular, we report data on the decay kinetics of the emission signals of extrinsic oxygen deficient centres of the second type from singlet and directly excited triplet states, and we use them as a probe of structural inhomogeneity. Luminescence activity in sapphire (alpha-Al(2)O(3)) is studied as well and used as a model system to compare the optical properties of defects in silica with those of defects embedded in a crystalline matrix. Only for defects in silica did we observe a variation of the decay lifetimes with emission energy and a time dependence of the first moment…
Inhomogeneous Broadening of Photoluminescence Spectra and Kinetics of Nanometer-Thick (Phenethylammonium)2PbI4 Perovskite Thin Films: Implications fo…
2021
An outstanding potentiality of layered two-dimensional (2D) organic–inorganic hybrid perovskites (2DHPs) is in the development of solar cells, photodetectors, and light-emitting diodes. In 2DHPs, an exciton is localized in an atomically thin lead(II) halide inorganic layer of sub-nanometer thickness as in a quantum well sandwiched between organic layers as energetic and dielectric barriers. In previous years, versatile optical characterization of 2DHPs has been carried out mainly for thin flakes of single crystals and ultrathin (of the order of 20 nm) polycrystalline films, whereas there is a lack of optical characterization of thick (hundreds of nanometers) polycrystalline films, fundament…
Features of level broadening in a ring-stub system
2000
When a one dimensional (1D) ring-stub system is coupled to an electron reservoir, the states acquire a width (or broadening characterized by poles in the complex energy plane) due to finite life time effects. We show that this broadening is limited by anti-resonances due to the stub. The differences in level broadening in presence and absence of anti-resonance is exemplified by comparison to a 1D ring coupled to an infinite reservoir. We also show that the anti-resonances due to the stub has an anchoring effect on the poles when a magnetic flux through the ring is varied. This will have implication on change in distribution of the poles in disordered multichannel situation as magnetic flux …
Pressure broadening, shift, and interference effect for a multiplet line in the rovibrational anisotropic stimulated raman spectrum of molecular oxyg…
1996
0022-2852; High-resolution stimulated inverse Raman spectroscopy has been applied to the study of collisional broadening, shifting, and line mixing for the O-o(J, N = 5) triplet line of the fundamental vibrational band of molecular oxygen. Accurate line broadening coefficients for the individual J components within the triplet have been measured for the first time and show a significant J dependence. The line broadening coefficients are larger than those previously obtained for unresolved pure rotational Raman lines. The additional broadening is expected to result from electronic spin relaxation. The pressure-induced line shift has been obtained for this Line and compared to the value obtai…
Dynamic properties of some β-chain mutant hemoglobins
1995
The thermal behavior of the Soret band relative to the carbonmonoxy derivatives of some beta-chain mutant hemoglobins is studied in the temperature range 300-10 K and compared to that of wild-type carbonmonoxy hemoglobin. The band profile at various temperatures is modeled as a Voigt function that accounts for homogeneous broadening and for the coupling with high- and low-frequency vibrational modes, while inhomogeneous broadening is taken into account with a gaussian distribution of purely electronic transition frequencies. The various contributions to the over-all bandwidth are singled out with this analysis and their temperature dependence, in turn, gives information on structural and dy…